Investigation of fast reactions of sterically hindered aroxyl radicals |
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Authors: | A I Prokof'ev N A Malysheva N N Bubnov S P Solodovnikov M I Kabachnik |
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Institution: | 1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow
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Abstract: | 1. |
A method is proposed for investigating fast reactions of aroxyl radicals. The kinetic parameters obtained for the reaction of 2,4,6-tri-t-butylphenoxyl with phenol and with 4-bromophenol coincide with the data obtained by other methods.
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From an analysis of the kinetic data, it is concluded that the OH bond energy in 4-methyl-2,6-di-t-butylphenol is close to that in 2,4,6-tri-t-butylphenol.
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