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Investigation of fast reactions of sterically hindered aroxyl radicals
Authors:A I Prokof'ev  N A Malysheva  N N Bubnov  S P Solodovnikov  M I Kabachnik
Institution:1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow
Abstract:
1.  A method is proposed for investigating fast reactions of aroxyl radicals. The kinetic parameters obtained for the reaction of 2,4,6-tri-t-butylphenoxyl with phenol and with 4-bromophenol coincide with the data obtained by other methods.
2.  From an analysis of the kinetic data, it is concluded that the OH bond energy in 4-methyl-2,6-di-t-butylphenol is close to that in 2,4,6-tri-t-butylphenol.
Keywords:
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