First metal azide complex with isonicotinate as a bridging ligand showing new net topology: hydrothermal synthesis, structure, and magnetic properties |
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| Authors: | Liu Fu-Chen Zeng Yong-Fei Jiao Jiao Bu Xian-He Ribas Joan Batten Stuart R |
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| Institution: | Department of Chemistry, Nankai University, Tianjin 300071, China. |
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| Abstract: | A new 3D azido-bridged coordination polymer, Co1.5(N3)(OH)(Isonic)]n (1), has been synthesized and characterized and its magnetic properties studied. Isonicotinate acts as a bridging coligand in this complex. In 1, all of the ligands take tridentate bridging coordination modes, and the overall structure of 1 exhibits a new 3,6-connected net topology. |
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