Reaction of the Heteronuclear Cluster RuOs3(μ − H)2(CO)13 with Diphenylacetylene: An Alkyne Bound to a Tetrahedral Metal Core |
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| Authors: | Yong Leng Kelvin Tan Chin Wai Alaric Koh Ting Bin Lim Weng Kee Leong |
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| Affiliation: | (1) Department of Chemistry, National University of Singapore, Kent Ridge, Singapore, 119260 |
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| Abstract: | Reaction of the heteronuclear cluster RuOs3(μ−H)2(CO)13, 1, with diphenylacetylene afforded the tetrahedral cluster RuOs3(μ−H)2(μ3,η1:η2:η1−C2Ph2)(CO)11, 2, in good yield. Spectroscopic evidence suggests that 2 exist as two isomers in solution. |
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| Keywords: | ruthenium osmium heteronuclear cluster isomers alkyne |
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