| A FOURIER TRANSFORM INFRARED SPECTROSCOPIC STUDY OF THE REACTION BETWEEN POLY (VINYL PYRIDINE)S AND EPOXY COMPOUNDS |
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| 引用本文： | 薛奇,江善根. A FOURIER TRANSFORM INFRARED SPECTROSCOPIC STUDY OF THE REACTION BETWEEN POLY (VINYL PYRIDINE)S AND EPOXY COMPOUNDS[J]. 高分子科学, 1987, 0(2): 133-140 |
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| 作者姓名： | 薛奇 江善根 |
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| 作者单位： | Department of Chemistry Nanjing University Nanjing，Department of Chemistry Nanjing University Nanjing |
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| 基金项目： | Projects supported by the Science Fund of the Chinese Academy of Science |
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| 摘 要： | Chemical reactions between poly (vinyl pyridine)s and 1, 4-butanediol diglycidyl ether and other epoxy compounds were studied by Fourier transform infrared spectroscopy and other techniques. The epoxy group was found to react with the pyridine side group of poly (4-vinyl pyridine), forming crosslinked networks which contain cyclic amide structures. The reaction was also observed in the interracial region of poly(vinyl pyridine) and γ-glycidoxy propyl trimethoxysilane hydrolyzate (γ-GPS) coatings on PET fiber substrates. Poly(2-vinyi pyridine) does not show the same reaction.
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| 收稿时间： | 1986-04-17 |
A FOURIER TRANSFORM INFRARED SPECTROSCOPIC STUDY OF THE REACTION BETWEEN POLY (VINYL PYRIDINE)S AND EPOXY COMPOUNDS* |
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| XUE Gi JIANG Shankeng. A FOURIER TRANSFORM INFRARED SPECTROSCOPIC STUDY OF THE REACTION BETWEEN POLY (VINYL PYRIDINE)S AND EPOXY COMPOUNDS*[J]. Chinese Journal of Polymer Science, 1987, 0(2): 133-140 |
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| Authors: | XUE Gi JIANG Shankeng |
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| Affiliation: | Department of Chemistry Nanjing University Nanjing; Department of Chemistry Nanjing University Nanjing |
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| Abstract: | Chemical reactions between poly (vinyl pyridine)s and 1, 4-butanediol diglycidyl ether and other epoxy compounds were studied by Fourier transform infrared spectroscopy and other techniques. The epoxy group was found to react with the pyridine side group of poly (4-vinyl pyridine), forming crosslinked networks which contain cyclic amide structures. The reaction was also observed in the interracial region of poly(vinyl pyridine) and γ-glycidoxy propyl trimethoxysilane hydrolyzate (γ-GPS) coatings on PET fiber substrates.poly(2-vinyl pyridine)does not show the same reaction. |
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| Keywords: | poly(4-vinyl pyridine) poly(2-vinyl pyridine) epoxy compound cyclic amide FTIR PET fiber interfacial reaction |
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