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Facile Green Synthesis of BCN Nanosheets as High‐Performance Electrode Material for Electrochemical Energy Storage |
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| Authors: | Indrapal Karbhal Rami Reddy Devarapalli Joyashish Debgupta Vijayamohanan K Pillai Pulickel M Ajayan Manjusha V Shelke |
| Institution: | 1. Physical & Materials Chemistry Division, CSIR-National Chemical Laboratory (CSIR-NCL), Pune, MH, India;2. Academy of Scientific and Innovative Research (AcSIR), Chennai, TN, India;3. CSIR-Network Centre for Solar Energy, CSIR-NCL, Pune, India;4. CSIR-Central Electrochemical Research Institute (CSIR-CECRI), Karaikudi, India;5. Department of Mechanical Engineering & Material Science, Rice University, Houston, TX, USA |
| Abstract: | Two‐dimensional hexagonal boron carbon nitride (BCN) nanosheets (NSs) were synthesized by new approach in which a mixture of glucose and an adduct of boric acid (H3BO3) and urea (NH2CONH2) is heated at 900 °C. The method is green, scalable and gives a high yield of BCN NSs with average size of about 1 μm and thickness of about 13 nm. Structural characterization of the as‐synthesized material was carried out by several techniques, and its energy‐storage properties were evaluated electrochemically. The material showed excellent capacitive behaviour with a specific capacitance as high as 244 F g?1 at a current density of 1 A g?1. The material retains up to 96 % of its initial capacity after 3000 cycles at a current density of 5 A g?1. |
| Keywords: | boron doping electrochemistry nanoparticles nitrides |