Crystal growth, defect structure and magnetism of new Li3N-derived lithium nitridocobaltates |
| |
| Authors: | Gordon Alexandra G Smith Ronald I Wilson Claire Stoeva Zlatka Gregory Duncan H |
| |
| Institution: | School of Chemistry, University of Nottingham, University Park, Nottingham, UK NG7 2RD. |
| |
| Abstract: | New nitridocobaltates Li(3-x-y)Co(x)N are revealed to contain significant Li(+) vacancies (y approximately 0.45) disordered within lithium-nitrogen planes and to exist as partially delocalised spin systems as a result of increased covalency through infinite -N-(Li,Co)-N- chains. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
