The anion-directed self-assembly of manganese complexes derived from 2-ethoxy-6-[(2-phenylaminoethylimino)methyl]phenol |
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| Authors: | Zhong-Lu You Mei Zhang Dong-Mei Xian Hai-Hua Li Qian-Feng Weng |
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| Affiliation: | (1) Department of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, 116029, People’s Republic of China |
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| Abstract: | The mixed valence manganese(II/IV) complex, [MnIIL2(MeOH)2]·[MnIVL2(OAc)2]·2(MeOH) (1), and the chloride-bridged 1D polymeric manganese(III) complex, [MnIIIL2(μ-Cl)]n (2), where L is the deprotonated form of 2-ethoxy-6-[(2-phenylaminoethylimino)methyl]phenol (HL), have been prepared and structurally characterized by single-crystal X-ray diffraction analysis and IR spectra. The Mn atoms in both complexes are octahedrally coordinated. The self-assembly of the complex structures is apparently directed by the anions of the manganese salts. |
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