| 2D NMR研究D-葡萄糖衍生的手性配体的绝对构型 |
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| 引用本文： | 黄汉民,黄为,韩秀文,陈惠麟,郑卓. 2D NMR研究D-葡萄糖衍生的手性配体的绝对构型[J]. 波谱学杂志, 2003, 20(3): 271-275 |
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| 作者姓名： | 黄汉民 黄为 韩秀文 陈惠麟 郑卓 |
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| 作者单位： | 中国科学院大连化学物理研究所，辽宁大连 116023 |
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| 基金项目： | 国家自然科学基金;29933050; |
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| 摘 要： | 应用二维NOSEY技术，对以D-葡萄糖为手性源合成的3种新型手性配体的结构和绝对构型进行了研究，并对此类化合物进行了计算机分子模拟，取得与NOSEY一致的结果. 此项研究对进一步研究手性配体在不对称催化反应中的构效关系提供了有力的帮助.
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| 关 键 词： | 核磁共振 NOSEY 计算机分子模拟 手性配体 绝对构型 |
| 收稿时间： | 2003-01-27 |
STUDY ON THE SYNTHESIS AND ABSOLUTE CONFIGURATIONS OF NOVEL CHIRAL LIGANDS DERIVED FROM D-GLUCOSE BY 2D NMR |
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| Abstract. STUDY ON THE SYNTHESIS AND ABSOLUTE CONFIGURATIONS OF NOVEL CHIRAL LIGANDS DERIVED FROM D-GLUCOSE BY 2D NMR[J]. Chinese Journal of Magnetic Resonance, 2003, 20(3): 271-275 |
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| Authors: | Abstract |
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| Affiliation: | Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023, China |
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| Abstract: | The two dimensional Nuclear Overhauser Effect Spectroscopy (NOESY) technique was successfully applied to investigate the structures and absolute configurations of novel chiral ligands which were derived from D glucose. The results have also been confirmed by computational optimizing model data. |
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| Keywords: | NMR NOESY Computational optimizing Chiral ligands Absolute configuration |
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