Excimer formation in the interlayer region of arene-derivatized zirconium phosphonates |
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Authors: | Amicangelo Jay C Leenstra Willem R |
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Affiliation: | Department of Chemistry, University of Vermont, Burlington, VT 05405, USA. |
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Abstract: | Photophysical investigations are reported for two arene-derivatized zirconium phosphonates (layered solids). The chromophore groups that are attached within the interlayer region of these materials are seen to form excimer pairs. Whereas the naphthalene-containing system exhibits both monomer and excimer fluorescence, the potentially greater overlap of chromophores for the system containing anthracene-pendant groups causes that compound to only show excimer fluorescence. |
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