Ternary (liquid + liquid) equilibria of the azeotrope (ethyl acetate + 2-propanol) with different ionic liquids at T = 298.15 K |
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Authors: | AB Pereiro |
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Institution: | Chemical Engineering Department, Vigo University, P.O. Box 36210, Vigo, Spain |
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Abstract: | Experimental (liquid + liquid) equilibria involving ionic liquids {1,3-dimethylimidazolium methyl sulfate (MMIM MeSO4)}, {2-propanol + ethyl acetate + 1-butyl-3-methylimidazolium hexafluorophosphate (BMIM PF6)} and {2-propanol + ethyl acetate + 1-hexyl-3-methylimidazolium hexafluorophosphate (HMIM PF6)} were carried out to separate the azeotropic mixture ethyl acetate and 2-propanol. Selectivity and distribution ratio values, derived from the tie-lines data, were presented in order to analyze the best separation solvent in a liquid extraction process. Experimental (liquid + liquid) equilibria data were compared with the correlated values obtained by means of the NRTL, Othmer-Tobias and Hand equations. These equations were verified to accurately correlate the experimental data. |
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Keywords: | Ionic liquids (Liquid + liquid) equilibria Correlative equations Azeotropes |
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