Self-recognition in the coordination-driven self-assembly of three-dimensional M3L2 polyhedra |
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Authors: | Yang Hai-Bo Ghosh Koushik Northrop Brian H Stang Peter J |
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Affiliation: | Department of Chemistry, University of Utah, 315 South 1400 East, RM 2020, Salt Lake City, Utah 84112, USA. |
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Abstract: | [reaction: see text] Self-recognition in the coordination-driven self-assembly of three-dimensional (3-D) polyhedra is described. Multiple discrete 3-D polyhedra were formed in one vessel through the self-recognition of a mixture of subunits. The dynamic self-recognition process is determined by the information stored within the geometry and directionality of multiple rigid building blocks as well as the thermodynamic stability of the discrete products. |
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