| Synthesis and Characterization of Tetrametal Cluster〔Co_2(CO)_6〕〔μ-HC_2CH_2OCH_2C_2H-μ〕〔Co_2(CO)_6〕 |
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| 引用本文： | CHEN XueNian ZHANG Jie YIN YuanQi (State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics,the Chinese Academy of Sciences,Lanzhou 730000) SUN Jie (Shanghai Institute of Organic Chemistry,the Chinese Ac. Synthesis and Characterization of Tetrametal Cluster〔Co_2(CO)_6〕〔μ-HC_2CH_2OCH_2C_2H-μ〕〔Co_2(CO)_6〕[J]. 结构化学, 1999, 0(4) |
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| 作者姓名： | CHEN XueNian ZHANG Jie YIN YuanQi (State Key Laboratory for Oxo Synthesis and Selective Oxidation Lanzhou Institute of Chemical Physics the Chinese Academy of Sciences Lanzhou 730000) SUN Jie (Shanghai Institute of Organic Chemistry the Chinese Ac |
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| 作者单位： | CHEN XueNian ZHANG Jie YIN YuanQi (State Key Laboratory for Oxo Synthesis and Selective Oxidation，Lanzhou Institute of Chemical Physics，the Chinese Academy of Sciences，Lanzhou 730000 |
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| 摘 要： | １ＩＮＴＲＯＤＵＣＴＩＯＮＩｎｔｅｎｓｅｉｎｔｅｒｅｓｔｉｎｔｒａｎｓｉｔｉｏｎ ｍｅｔａｌｃｌｕｓｔｅｒｓｃｏｎｔｉｎｕｅｓｂｅｃａｕｓｅｔｈｅｙｒｅｐｒｅｓｅｎｔｐｏｓ ｓｉｂｌｅｃｏｎｃｅｐｔｕａｌｂｒｉｄｇｅｓｂｅｔｗｅｅｎｈｏｍｏｇｅｎｅｏ...
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Synthesis and Characterization of Tetrametal Cluster=Co2(CO)6HC2CH2OCH2C2HCo2(CO)6 |
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| CHEN XueNian ZHANG Jie YIN YuanQi. Synthesis and Characterization of Tetrametal Cluster=Co2(CO)6HC2CH2OCH2C2HCo2(CO)6[J]. Chinese Journal of Structural Chemistry, 1999, 0(4) |
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| Authors: | CHEN XueNian ZHANG Jie YIN YuanQi |
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| Abstract: | The treatment of dipropargyl ether HC2CH2OCH2C2H with Co2(CO)8 resulted in the formation of a novel cluster Co2(CO)6HC2CH2OCH2C2HCo2(CO)6. The cluster was characterized by C/H analyses, IR and 1H NMR spectroscopy and Xray crystal structure determination. It belongs to monoclinic system, space group P21/c with the following crystallographic parameters: a=18.149(2), b=7.0111(7), c=20.897(2) , =115.318(7), V=2403.7(5) 3, Z=4, Mr=665.97, Dc=1.840 gcm-3, F(000)=1304.00, (MoK)=27.76 cm-1 and R=0.030 for 2372 observed reflections. |
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| Keywords: | cobalt dipropargyl ether carbonyl crystal structure |
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