The kinetics of hydroxyl radical reactions with cyclopropane and cyclobutane |
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| Affiliation: | (1) Central Research Institute for Chemistry, Hungarian Academy of Science, P.O. Box 17, H-1525 Budapest, Hungary |
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| Abstract: | A laser flash photolysis/resonance fluorescence investigation has been carried out to study the kinetics of the overall reactions OH + cyclopropane (1) and OH + cyclobutane (2) in the temperature range 298–490 K and at 298 K, respectively. The following kinetic parameters have been determined: k1 =(3.9 ±0.6) 10−12exp- (2.2 ± 0.1)kcal mol−1/RT molecule−1cm3s−1, k2(298 K) = (17.5 ± 1.5)10−13molecule−1 cm3s−1. |
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| Keywords: | Reaction kinetics OH radicals cycloalkanes |
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