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Chlorination of aliphatic hydrocarbons, aromatic compounds, and olefins in subcritical carbon tetrachloride
Authors:Kiyoshi Tanemura  Tsuneo Suzuki  Takaaki Horaguchi
Institution:a School of Life Dentistry at Niigata, The Nippon Dental University, Hamaura-cho, Niigata 951-8580, Japan
b Department of Chemistry, Faculty of Science, Niigata University, Ikarashi, Niigata 950-2181, Japan
Abstract:The reactions of various substrates including aliphatic hydrocarbons, aromatic compounds, and olefins were investigated in subcritical carbon tetrachloride. Ketones and sulfones were stable under the employed conditions. The coupling adducts between olefins and carbon tetrachloride were obtained from the reactions of olefins.
Keywords:High temperature reactions  Subcritical conditions  Chlorination  Carbon tetrachloride
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