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A novel combination of (diacetoxyiodo)benzene and tert-butylhydroperoxide for the facile oxidative dehydrogenation of 3,4-dihydropyrimidin-2(1H)-ones
Authors:Nandkishor N Karade  Sumit V Gampawar  Jeevan M Kondre  Girdharilal B Tiwari
Institution:School of Chemical Sciences, Swami Ramanand Teerth Marathwada University, Nanded 431 606, Maharashtra, India
Abstract:A clean and efficient oxidative dehydrogenation of 3,4-dihydropyrimidin-2(1H)-ones to 1,2-dihydropyrimidines has been achieved through a novel combination of (diacetoxyiodo)benzene and tert-butylhydroperoxide in CH2Cl2.
Keywords:Biginelli reaction  Dehydrogenation  1  2-Dihydropyrimidine  Hypervalent iodine  (Diacetoxyiodo)benzene  tert-Butylhydroperoxide
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