On the use of the modified Julia olefination for bryostatin synthesis |
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| Authors: | Joanne V. Allen Simon Hardy Alan T.L. Lee |
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| Affiliation: | a AstraZeneca, Mereside, Alderley Park, Macclesfield, Cheshire SK10 4TG, UK
b The School of Chemistry, The University of Manchester, Manchester M13 9PL, UK |
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| Abstract: | Modified Julia olefination reactions using aldehyde 27 and the benzothiazol-2-yl sulfones 13 and 39 provide efficient syntheses of alkenes 28 and 42, which are advanced intermediates for syntheses of bryostatins. |
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