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Novel cleavage of (E)-allyl vic-diols to aldehydes using the 2nd-generation Grubbs catalyst |
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| Authors: | Chunguang Han |
| Institution: | a Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chikusa, Nagoya 464-8602, Japan b Department of Biosciences and Informatics, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Yokohama 223-8522, Japan |
| Abstract: | Secondary (E)-allyl vic-diol cleavage in the presence of the 2nd-generation Grubbs catalyst has been developed. The position of a vic-diol adjacent to C C plays a crucial role in the cleavage reaction compared to an alkyl vic-diol based on a model compound. |
| Keywords: | (E)-allyl vic-diol Cleavage 2nd-Generation Grubbs catalyst Alkyl vic-diol |
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