Adenine-based urea receptors in fluorescent recognition of iodide |
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Authors: | Kumaresh Ghosh Tanushree Sen |
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Institution: | Department of Chemistry, University of Kalyani, Kalyani 741 235, India |
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Abstract: | Adenine-based receptors 1 and 2 are designed and synthesized for selective sensing of iodide over the other halides and carboxylate anions. Both the receptors 1 and 2 use the urea motif for binding carboxylates and halides. Emissions of the naphthalene and the anthracene in 1 and 2, respectively, are monitored in CHCl3 in detecting the anions. While carboxylates, fluoride, chloride, and bromide increase the emissions of naphthalene and anthracene in both the receptors 1 and 2 during complexation, iodide quenches the emission. Such selective quenching allows iodide to be discriminated from other halides and carboxylate anions. |
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Keywords: | Adenine-based urea Naphthalene Sensors Carboxylate anions Iodide recognition |
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