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A synthetic approach to the functionalized hydroazulene core of guanacastepenes and heptemerenes
Authors:Karol Michalak
Institution:Institute of Organic Chemistry, Polish Academy of Sciences, ul. Kasprzaka 44/52, 01-224 Warsaw 42, Poland
Abstract:A functionalized hydroazulene derivative has been synthesized efficiently from 2-methylcyclopent-2-en-1-one as a part of a study oriented toward the total synthesis of diterpenoids of biological significance, guanacastepenes, and heptemerones.
Keywords:Diterpenoids  Michael addition  Annulation  Regioselective transformations
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