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A catalytic asymmetric vinylogous Mukaiyama aldol reaction |
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| Authors: | Heumann Lars V Keck Gary E |
| Institution: | Department of Chemistry, University of Utah, 315 South 1400 East RM 2020, Salt Lake City, Utah 84112-0850, USA. |
| Abstract: | A vinylogous Mukaiyama aldol reaction, conducted using 10 mol % of a BITIP catalyst and B(OMe)3 as an additive, effects an enantioselective four-carbon chain extension to give versatile E-alpha,beta-unsaturated thiol esters. |
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