Some new acrylate complexes as a criterion in their selection for further co-polymerization reaction |
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| Authors: | M Badea R Olar D Marinescu G Vasile |
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| Institution: | (1) University of Bucharest, Faculty of Chemistry, Department of Inorganic Chemistry, 90-92 Panduri St., 050663 Sector 5, Bucharest, Romania;(2) University of Bucharest, Faculty of Chemistry, Department of Inorganic Chemistry, 90-92 Panduri St., 050663 Sector 5, Bucharest, Romania;(3) University of Bucharest, Faculty of Chemistry, Department of Inorganic Chemistry, 90-92 Panduri St., 050663 Sector 5, Bucharest, Romania;(4) University of Agronomical Sciences and Veterinary Medicine, Department of Agrochemistry, Bd. Marasti 59, Bucharest, Romania |
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| Abstract: | Summary This paper reports the investigation of the thermal stability of a series of new complexes with mixed ligands of the type M(phen)(C3H3O2)2(H2O)y ((1) M=Mn, y=0; (2) M=Ni, y=2; (3) M=Cu, y=1; (4) M=Zn, y=2; phen=phenanthroline and C3H3O2 is acrylate anion). The thermal behaviour steps were investigated. The thermal transformations are complex processes according to TG and DTG curves including dehydration, oxidative condensation of acrylate and thermolysis processes. The final products of decomposition are the most stable metal oxides. |
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| Keywords: | complexes thermal stability acrylate fumarate |
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