| 含八齿苦味酸根的超分子苦味酸钾的合成和结构 |
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| 引用本文： | 董文魁,宋学琴,孙银霞,吴辉禄.含八齿苦味酸根的超分子苦味酸钾的合成和结构[J].无机化学学报,2007,23(10):1809-1811. |
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| 作者姓名： | 董文魁 宋学琴 孙银霞 吴辉禄 |
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| 作者单位： | 兰州交通大学化学与生物工程学院,兰州,730070 |
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| 基金项目： | 甘肃省教育厅科研项目;兰州交通大学校科研和教改项目 |
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| 摘 要： | A supramolecular complex， Kpic]n (pic- is picratol， (NO2)3C6H2O-)， has been synthesized unexpectedly in acetone solution， and characterized by elemental analysis， IR and X-ray crystallography. In the complex， the K+∶pic- is 1∶1， and one K(Ⅰ) ion is surrounded by six picrate anions， one picrate anion can coordinate to six K(Ⅰ) ions. The coordination number of every potassium atom is eight. Interestingly， the picratol adopts an eight-coordinated ideal mode unreported. CCDC: 630627.
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| 关 键 词： | 钾(Ⅰ)配合物 合成 晶体结构 |
| 文章编号： | 1001-4861（2007）10-1809-03 |
| 修稿时间： | 2007-06-18 |
Synthesis and Crystal Structure of Supramolecular Potassium Picrate Bearing Octadentate μ-Picrate Bridges |
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| DONG Wen-Kui,SONG Xue-Qin,SUN Yin-Xia and WU Hui-Lu.Synthesis and Crystal Structure of Supramolecular Potassium Picrate Bearing Octadentate μ-Picrate Bridges[J].Chinese Journal of Inorganic Chemistry,2007,23(10):1809-1811. |
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| Authors: | DONG Wen-Kui SONG Xue-Qin SUN Yin-Xia and WU Hui-Lu |
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| Institution: | School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070 |
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| Abstract: | A supramolecular complex, Kpic]n (picˉ is picratol, (NO2)3C6H2Oˉ), has been synthesized unexpectedly in acetone solution, and characterized by elemental analysis, IR and X-ray crystallography. In the complex, the ions. The coordination number of every potassium atom is eight. Interestingly, the picratol adopts an eightcoordinated ideal mode unreported. CCDC: 630627. |
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| Keywords: | synthesis crystal structure |
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