Phase Transformations in Formation of Layered Perovskites from Coprecipitated Components |
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Authors: | Titov Yu A Slobodyanik N S |
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Institution: | (1) Taras Shevchenko Kyiv National University, 64 Volodymyrs'ka Vul., 01033 Kyiv, Ukraine |
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Abstract: | We have determined the characteristic features of formation of layered perovskite-like compounds of the type A
n
B
n
O3n+2 (n = 5, 6) from systems of coprecipitated hydroxides or hydroxocarbonates. We have established that the process of formation of the crystalline five-layer or six-layer perovskite-like structure of compounds of the A
n
B
n
O3n+2 type occurs only according to a two-step mechanism. |
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Keywords: | layered perovskite-like compounds mechanisms of formation |
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