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Phase Transformations in Formation of Layered Perovskites from Coprecipitated Components
Authors:Titov  Yu A  Slobodyanik  N S
Institution:(1) Taras Shevchenko Kyiv National University, 64 Volodymyrs'ka Vul., 01033 Kyiv, Ukraine
Abstract:We have determined the characteristic features of formation of layered perovskite-like compounds of the type A n B n O3n+2 (n = 5, 6) from systems of coprecipitated hydroxides or hydroxocarbonates. We have established that the process of formation of the crystalline five-layer or six-layer perovskite-like structure of compounds of the A n B n O3n+2 type occurs only according to a two-step mechanism.
Keywords:layered perovskite-like compounds  mechanisms of formation
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