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Limiting polytope geometry for rigid rods,disks, and spheres
Authors:Frank H. Stillinger Jr.  Zevi W. Salsburg
Affiliation:(1) Bell Telephone Laboratories, Inc., 07974 Murray Hill, New Jersey;(2) Department of Chemistry, Rice University, 77001 Houston, Texas
Abstract:The available configuration space for finite systems of rigid particles separates into equivalent disconnected regions if those systems are highly compressed. This paper presents a study of the geometric properties of the limiting high-compression regions (polytopes) for rods, disks, and spheres. The molecular distribution functions represent cross sections through the convex polytopes, and for that reason they are obliged to exhibit single-peak behavior by the Brünn-Minkowski inequality. We demonstrate that increasing system dimensionality implies tendency toward nearest-neighbor particle-pair localization away from contact. The relation between the generalized Euler theorem for the limiting polytopes and cooperative ldquojammingrdquo of groups of particles is explored. A connection is obtained between the moments of inertia of the polytopes (regarded as solid homogeneous bodies) and crystal elastic properties. Finally, we provide a list of unsolved problems in this geometrical many-body theory.
Keywords:Rigid spheres  Rigid disks  Rigid rods  Elasticity  High pressure  Polytopes  Convexity  Crystal anharmonicity  Pair correlation functions  Multidimensional geometry  Crystalline order  Crystal defects
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