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Nucleophilic trifluoromethylation of organic substrates using (trifluoromethyl)trimethylsilane in the presence of a fluoride anion II. A convenient route to aryltrifluoromethyl-sulfides, -sulfoxides and -sulfones |
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| Authors: | Valeria N Movchun Alexander A Kolomeitsev Yurii L Yagupolskii |
| Institution: | Institute of Organic Chemistry, Ukrainian Academy of Sciences, 253660, Kiev-94, Ukraine |
| Abstract: | Aryltrifluoromethyl-sulfides, -sulfoxides and -sulfones can be prepared by trifluoromethylation of the corresponding arylsulfenyl, -sulfinyl and -sulfonyl halides using (trifluoromethyl)trimethylsilane in the presence of fluoride sources, such as TASF tris(dimethylamino)sulfonium difluorotrimethylsilicate]. |
| Keywords: | Nucleophilic trifluoromethylation (Trifluoromethyl)trimethylsilane Fluoride anion Aryltrifluoromethylsulfides Aryltrifluoromethylsulfoxides Aryltrifluoromethylsulfones |
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