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Isotope exchange between iron(II or III) hydroxide and HTO water in the equilibrium state
Authors:H Imaizumi  N Kano  M Eguchi
Institution:(1) Department of Chemistry and Chemical Engineering, Faculty of Engineering, Niigata University, 950-21 Ikarashi, Niigata, Japan
Abstract:Observing the OT-for-OH exchange reaction between iron(II or III) hydroxide and tritiated water (HTO) leads to the following results: (1) isotope exchange as ldquoatomic grouprdquo occurred between the OH group in each iron hydroxide (i.e., Fe(OH)2 or Fe(OH)3) and OT resulted from the dissociation of HTO; (2) the ratio of the reactivity of the hydroxides is roughly iron(III) hydroxide]: iron(II) hydroxide]=1.2ratio1.0 and the result is related to a difference in electronegativity between Fe2+ and Fe3+. (In other words, if the reactivity depends on the number of the charge, the ratio should be 1.5ratio1.0).
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