Coordination compounds of [Hg{PPh2[M(CO)5]}2], (M = Cr, Mo, W) |
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Authors: | Paul Peringer |
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Abstract: | Coordination of various neutral N and O ligands causes drastic changes in 1J(31P-199Hg) (increase up to the threefold) and δ(31P) (shifts up to 30 ppm to low frequencies), which are due to the presence of the M(CO)5 groups. The complexes with DMSO, phen and bipy were isolated in the solid state. No coordination of [Hg{PCy2[Cr(CO)5]}2] with the above ligands is observed. |
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