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Phane properties of [2.2]paracyclophane/dehydrobenzoannulene hybrids
Authors:Hinrichs Heino  Boydston Andrew J  Jones Peter G  Hess Kirsten  Herges Rainer  Haley Michael M  Hopf Henning
Affiliation:Institut für Organische Chemie, Technische Universit?t Braunschweig, Hagenring 30, 38106 Braunschweig, Germany.
Abstract:A series of [2.2]paracyclophane/dehydrobenzo[14]annulene (PC/DBA) hybrids (hydrocarbons 5, 6, 9, 10 b, and 10 c), [2.2]paracyclophane/dehydro[14]annulene (PC/DA) hybrids (7 and 8) and suitable model systems (11, 12, and 33) has been synthesized. Comparison of the electronic absorption spectra in each series of compounds provides further insight into the global communication between the decks in the [2.2]paracyclophane unit.
Keywords:annulenes  coupling reactions  cyclophanes  electronic interactions  electronic spectra
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