Phane properties of [2.2]paracyclophane/dehydrobenzoannulene hybrids |
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| Authors: | Hinrichs Heino Boydston Andrew J Jones Peter G Hess Kirsten Herges Rainer Haley Michael M Hopf Henning |
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| Institution: | Institut für Organische Chemie, Technische Universit?t Braunschweig, Hagenring 30, 38106 Braunschweig, Germany. |
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| Abstract: | A series of 2.2]paracyclophane/dehydrobenzo14]annulene (PC/DBA) hybrids (hydrocarbons 5, 6, 9, 10 b, and 10 c), 2.2]paracyclophane/dehydro14]annulene (PC/DA) hybrids (7 and 8) and suitable model systems (11, 12, and 33) has been synthesized. Comparison of the electronic absorption spectra in each series of compounds provides further insight into the global communication between the decks in the 2.2]paracyclophane unit. |
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| Keywords: | annulenes coupling reactions cyclophanes electronic interactions electronic spectra |
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