| 聚丙烯酸修饰咔唑的电化学聚合及表征 |
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| 引用本文： | 朱召进,徐景坤,裴梅山,卢宝阳,马茶,李龙,申亮. 聚丙烯酸修饰咔唑的电化学聚合及表征[J]. 化学学报, 2010, 68(6): 564-570 |
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| 作者姓名： | 朱召进 徐景坤 裴梅山 卢宝阳 马茶 李龙 申亮 |
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| 作者单位： | 江西科技师范学院江西省有机功能分子重点实验室,南昌330013;济南大学化学化工学院,济南250022;江西科技师范学院江西省有机功能分子重点实验室,南昌,330013;济南大学化学化工学院,济南,250022 |
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| 基金项目： | 国家自然科学基金,教育部科学技术研究项目,江西省教育厅科研项目 |
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| 摘 要： | 合成了侧链带有咔唑的N-丙烯酰氧己基咔唑(MACZ),通过自由基聚合得到聚N-丙烯酰氧己基咔唑(PMACZ),在四氢呋喃含10%三氟化硼乙醚与四氟化硼四丁基胺的混合电解质溶液中,直接阳极氧化PMACZ获得自支撑交联网状的聚(聚N-丙烯酰氧己基咔唑)(PPMACZ)薄膜.PPMACZ薄膜具有良好的氧化还原性和热稳定性,电导率为1.34×10-5S·cm-1.1HNMR和红外光谱表明PMACZ二次聚合反应发生在咔唑单元的3,6位上,荧光光谱表明PPMACZ薄膜是一种良好的蓝色发光材料.
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| 关 键 词： | 聚咔唑 导电高分子 聚丙烯酸酯 电化学聚合 交联网状膜 |
| 收稿时间： | 2009-07-24 |
| 修稿时间： | 2009-10-04 |
Electrosynthesis and Characterization of Free-standing Polyacrylate Functionalized Polycarbazole Network Films |
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| Zhu Zhaojin,Xu Jingkun,Pei Meishan,Lu Baoyang,Ma Cha,Li Long,Shen Liang. Electrosynthesis and Characterization of Free-standing Polyacrylate Functionalized Polycarbazole Network Films[J]. Acta Chimica Sinica, 2010, 68(6): 564-570 |
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| Authors: | Zhu Zhaojin Xu Jingkun Pei Meishan Lu Baoyang Ma Cha Li Long Shen Liang |
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| Affiliation: | ( Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013)
(College of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022) |
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| Abstract: | A novel acrylate functionalized with pendant carbazole monomer, N-[6-(acryloxy)hexyl]-carbazole (MACZ), was synthesized. The radical polymerization of MACZ led to the formation of a precursor polymer, poly(N-[6-(acryloxy)hexyl]carhazole) (PMACZ). Free-standing and conducting conjugated polycarbazole network poly-{poly(N-[6-(acryloxy)hexyl]carbazole)} (PPMACZ) films were synthesized electrochemically by direct anodic oxidation of PMACZ, which showed good electrochemical behavior and good thermal stability with conductivity of 1.34 ×10~(-5) S·cm~(-1), and were characterized by UV-Vis, infrared,fluorescence spectroscopy and thermal analysis. Fluorescence spectral studies revealed that the PPMACZ films were good blue light emitters. |
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| Keywords: | polycarbazole conducting polymer polyacrylate electrochemical polymerization network film |
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