| Magnetic Properties of Phenoxy－Bridged Binuclear Iron－Thiolato Complexes and Structure of （Et_4N）_2［Fe_2（o－OC_6H_4S）_2（o－OC_6H_4SH）_2］ |
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| 引用本文： | XIE Xiu-Lan, XU Yong-Jin, WENG Lin-Hong, WU Da-Xu, HONG Mao-Chun, WEN Ting-Bin(State Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002)KANG Bei-Sheng(Department of. Magnetic Properties of Phenoxy－Bridged Binuclear Iron－Thiolato Complexes and Structure of （Et_4N）_2［Fe_2（o－OC_6H_4S）_2（o－OC_6H_4SH）_2］[J]. 结构化学, 1996, 0(5) |
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| 作者姓名： | XIE Xiu-Lan XU Yong-Jin WENG Lin-Hong WU Da-Xu HONG Mao-Chun WEN Ting-Bin(State Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou 350002)KANG Bei-Sheng(Department of |
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| 作者单位： | XIE Xiu-Lan; XU Yong-Jin; WENG Lin-Hong; WU Da-Xu; HONG Mao-Chun; WEN Ting-Bin(State Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter，Chinese Academy of Sciences，Fuzhou 350002 |
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| 摘 要： | ＭａｇｎｅｔｉｃＰｒｏｐｅｒｔｉｅｓｏｆＰｈｅｎｏｘｙ－ＢｒｉｄｇｅｄＢｉｎｕｃｌｅａｒＩｒｏｎ－ＴｈｉｏｌａｔｏＣｏｍｐｌｅｘｅｓａｎｄＳｔｒｕｃｔｕｒｅｏｆ（Ｅｔ_４Ｎ）_２［Ｆｅ_２（ｏ－ＯＣ_６Ｈ_４Ｓ）_２（ｏ－ＯＣ_６Ｈ_４ＳＨ）_２］ＸＩＥＸｉ?..
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Magnetic Properties of Phenoxy-Bridged Binuclear Iron-Thiolato Complexes and Structure of (Et_4N)_2[Fe_2(o-OC_6H_4S)_2(o-OC_6H_4SH)_2] |
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| XIE Xiu-Lan, XU Yong-Jin, WENG Lin-Hong, WU Da-Xu, HONG Mao-Chun, WEN Ting-Bin. Magnetic Properties of Phenoxy-Bridged Binuclear Iron-Thiolato Complexes and Structure of (Et_4N)_2[Fe_2(o-OC_6H_4S)_2(o-OC_6H_4SH)_2][J]. Chinese Journal of Structural Chemistry, 1996, 0(5) |
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| Authors: | XIE Xiu-Lan XU Yong-Jin WENG Lin-Hong WU Da-Xu HONG Mao-Chun WEN Ting-Bin |
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| Abstract: | The variable-temperature magnetic properties of the two phenoxybridged di-iron complexes(Et4N)2[Fe2(o-OC6H4S)4](1) and (Et4N)2[Fe2(o-OC6H4S)2(o-OC6H4SH)2] (2) with o-mercaptophenol ligand are reported. The J values obtained show weak antiferromagnetic interactions of the iron atoms in both complexes. The spin states are S=5/2 and S=1 for the Fe(Ⅲ) and Fe(Ⅱ) ions in (1) and (2), respectively. The crystal structure of (2) is also presented. |
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| Keywords: | magnetic property phenoxy-bridged di-iron complex spin state |
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