| CRYSTAL STRUCTURE OF A TRINUCLEAR COBALT COMPLEX Co_3(bdt)_3(PBu_3~n)_3 · ~2CH_2C1 (bdt = S_2C_6H_4~2- ) WITH MIXED o-BEN-ZENEDITHIOLATE AND TRIBUTYLPHOSPHINE LIGANDS |
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| 作者姓名： | Peng Jing-Hai Kang Bei-Sheng Hong Mao-Chun Weng Ling-HongFuzhou Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure ofMatter Chinese Academy of Sciences Fuzhou Fujian |
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| 作者单位： | Peng Jing-Hai Kang Bei-Sheng Hong Mao-Chun Weng Ling-HongFuzhou Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure ofMatter，Chinese Academy of Sciences，Fuzhou，Fujian 350002 |
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| 摘 要： | <正> Co3(S2C6H4)3{P(C4H9)3}3 ·2CH2Cl2, Mr = 1373. 45, mono-clinic, space group P21/c, a = 16. 110(5), b=36.313(10), c=13. 502(5) A , β= 105. 69(4)% V=7604. 4 A3, Z = 4, Dc = 1. 20 g. cm-3, μ=10. 03 cm-1, and F (000) = 2990. R(Rw) is 0. 086(0. 091) for 4559 observed unique reflections. The three cobalt atoms in the complex form an isosceles triangle with an average Co -Co bond distance of 2. 504(5) A. The average values of Co - S and Co - P bond distances are 2. 271(7) A , and 2. 198(8) A , respectively.
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CRYSTAL STRUCTURE OF A TRINUCLEAR COBALT COMPLEX Co_3(bdt)_3(PBu_3~n)_3 · ~2CH_2C1 (bdt = S_2C_6H_4~2- ) WITH MIXED o-BEN-ZENEDITHIOLATE AND TRIBUTYLPHOSPHINE LIGANDS |
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| Peng Jing-Hai Kang Bei-Sheng Hong Mao-Chun Weng Ling-HongFuzhou Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure ofMatter,Chinese Academy of Sciences,Fuzhou,Fujian .CRYSTAL STRUCTURE OF A TRINUCLEAR COBALT COMPLEX Co_3(bdt)_3(PBu_3~n)_3 · ~2CH_2C1 (bdt = S_2C_6H_4~2- ) WITH MIXED o-BEN-ZENEDITHIOLATE AND TRIBUTYLPHOSPHINE LIGANDS[J].Chinese Journal of Structural Chemistry,1993(5). |
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| Authors: | Peng Jing-Hai Kang Bei-Sheng Hong Mao-Chun Weng Ling-HongFuzhou Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure ofMatter Chinese Academy of Sciences Fuzhou Fujian |
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| Institution: | Peng Jing-Hai Kang Bei-Sheng Hong Mao-Chun Weng Ling-HongFuzhou Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure ofMatter,Chinese Academy of Sciences,Fuzhou,Fujian 350002 |
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| Abstract: | Co3(S2C6H4)3{P(C4H9)3}3 ·2CH2Cl2, Mr = 1373. 45, mono-clinic, space group P21/c, a = 16. 110(5), b=36.313(10), c=13. 502(5) A , β= 105. 69(4)% V=7604. 4 A3, Z = 4, Dc = 1. 20 g. cm-3, μ=10. 03 cm-1, and F (000) = 2990. R(Rw) is 0. 086(0. 091) for 4559 observed unique reflections. The three cobalt atoms in the complex form an isosceles triangle with an average Co -Co bond distance of 2. 504(5) A. The average values of Co - S and Co - P bond distances are 2. 271(7) A , and 2. 198(8) A , respectively. |
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| Keywords: | Trinuclear Cobalt Complex Crystal Structure |
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