| Synthesis and Crystal Structure of 1-Methylsulfinyl-1-methylthio-2-cyano-2-phenylethylene |
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| 引用本文： | 陈凯,杨华铮,翁林红,冷雪冰. Synthesis and Crystal Structure of 1-Methylsulfinyl-1-methylthio-2-cyano-2-phenylethylene[J]. 结构化学, 2000, 19(5) |
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| 作者姓名： | 陈凯 杨华铮 翁林红 冷雪冰 |
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| 作者单位： | National Key Laboratory and Institute of Elemento-Organic Chemistry，Nankai University，Tianjin，300071 |
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| 基金项目： | ProjectsupportedbytheNNSFofChina (No .2 9772 0 2 0 ) |
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| 摘 要： | 1 ＩＮＴＲＯＤＵＣＴＩＯＮＤｉｔｈｉｏａｃｅｔａｌｓ[1 3]ｈａｖｅｄｅｍｏｎｓｔｒａｔｅｄｔｈｅｉｒｐｏｔｅｎｔｉａｌｆｏｒｔｈｅｓｙｎｔｈｅｓｉｓｏｆｈｅｔｅｒｏｃｙ ｃｌｅｓ,ｔｈｅｒｅｆｏｒｅ ,ｔｈｅｉｒｓｙｎｔｈｅｓｉｓａｎｄｒｅａｃｔｉｏｎｓｈａｖｅａｔｔｒａｃｔｅｄｍｕｃｈａｔｔｅｎｔｉｏｎ ,ｂｕｔｖｅｒｙｌｉｔｔｌｅｈａｓｂｅｅｎｒｅｐｏｒｔｅｄａｂｏｕｔｔｈｅｏｘｉｄａｔｉｏｎｏｆｄｉｔｈｉｏａｃｅｔａｌｓ[4].Ａｃｃｏｒｄｉｎｇｔｏｔｈｅｐｒｅｖｉ ｏｕｓｒｅｐｏｒｔ,ｔｈｅｏｘｉｄ…
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Synthesis and Crystal Structure of 1-Methylsulfinyl-1-methylthio-2-cyano-2-phenylethylene |
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| CHEN Kai YANG Hua-Zheng WENG Lin-Hong LENG Xue-Bing. Synthesis and Crystal Structure of 1-Methylsulfinyl-1-methylthio-2-cyano-2-phenylethylene[J]. Chinese Journal of Structural Chemistry, 2000, 19(5) |
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| Authors: | CHEN Kai YANG Hua-Zheng WENG Lin-Hong LENG Xue-Bing |
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| Abstract: | The crystal of the title compound (C11H11 NOS2, Mr = 237.33) has been prepared and determined by X-ray single crystal diffraction. The crystal is monoclinic, space group P21/c with parameters: a = 5. 484 (1), b = 7. 793(2), c = 28. 295(6) A, β=90.277(4)°, V =1209. 2(5) A3, Z=4, Dc=1.034 g/cm3, μ(MoKα)=0.413 mm-1 F(000) = 496 the final R = 0. 0390 and w R = 0. 1051 for 1500 observed reflections with I ＞2σ (I). The X-ray analysis result shows that the orientation of methylsulfinyl and phenyl is the cis and confirms the E-stereochemistry of the title compound. |
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| Keywords: | crystal structure synthesis 1-methylsulfinyl-1-methylthio-2-cyano-2-phenylethylene |
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