Crystal and Molecular Structure of Copper(Ⅰ) Complex 〔Cu(PPh_3)_2(NO_3)〕 |
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作者姓名: | YANG Rui Na * LI Tian Xian SUN Yu An 1 HU Xiao Yuan JIN Dou Man LUO Bao Sheng 2 (Henan Institute of Chemistry Zhengzhou 450003) (State Key Laboratory of Coordination Chemistry Nanjing University 210093) 1(Zhengzhou Institute of |
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作者单位: | YANG Rui Na * LI Tian Xian SUN Yu An 1 HU Xiao Yuan JIN Dou Man LUO Bao Sheng 2 (Henan Institute of Chemistry,Zhengzhou 450003) (State Key Laboratory of Coordination Chemistry,Nanjing University 210093) 1(Zhengzhou Institute of |
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基金项目: | National Natural Science Foundation of China( No.2 98710 0 9) and State Key L ab.of Coordination Chemistry of Nanjing Uni-vers |
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摘 要: | 1 INTRODUCTIONCopper( ) displays a wide diversity in its structural chemistry,the copper co-ordination number ranging from two to four.Procedures to synthesize copper( )complexes are of greatinterestbecause of the diversity of products resulting from al-mostthe same methodology.Ithaslong been accepted thatcopper( ) complexesarediamagnetic and provide no optical absorption bands( no d- d transition isencountered) for a copper( ) ion with a d10 configuration and no electron spin reso-n…
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