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A practical method for regiocontrolled one-carbon ring contraction |
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| Authors: | Matthew J. Mitcheltree Zef A. Konst Seth B. Herzon |
| Affiliation: | Department of Chemistry, Yale University, New Haven, CT 06511, United States |
| Abstract: | A practical and efficient method for the perfluorobutanesulfonyl azide-mediated one-carbon ring contraction of cyclic enoxysilanes is described. High-yielding procedures for the elaboration of the resulting N-acyl sulfonamide products are reported. |
| Keywords: | Ring contraction Silyl-enol ether Enoxysilane Nonaflyl azide |
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