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Structural,optical and mechanical property analysis of magnesium sulphate admixtured l-Threonine: A novel optoelectronic material
Authors:A Puhal Raj  I John David Ebenezar  C Ramachandra Raja
Institution:1. Government Arts College (Autonomous), Kumbakonam, 612 001, Tamilnadu, India;2. Department of Physics, TBML College, Porayar, 609 307, Tamil Nadu, India
Abstract:l-Threonine is an important amino acid and famous due to their property of frequency conversion and electro optic modulation. Single crystals of magnesium sulphate admixtured l-Threonine was grown by slow evaporation technique. Good quality single crystal with dimension 58 × 5 × 10 mm3 was harvested after 60 days. The powder X-ray diffraction pattern of the grown crystal has been indexed. The optical transmission spectrum shows that the magnesium sulphate admixtured l-Threonine possess good optical transparency in the entire visible region with Ultra Violet cut-off wavelength at 250 nm. The presence of fundamental functional groups was identified by Fourier Transform Infra Red spectral analysis. The structure of the grown crystal was established using Fourier Transform-Nuclear Magnetic Resonance spectral analysis. The thermal behaviour of the crystal has been discussed by Thermal Gravimetric Analysis and Differential Thermal Analysis. Magnesium sulphate admixtured l-Threonine was characterized by Energy dispersive analysis of X-ray. The second harmonic generation efficiency of magnesium sulphate admixtured l-Threonine crystal is found to be same as that of potassium dihydrogen phosphate crystal.
Keywords:Crystal growth  Amino acid  Non linear optical material  X-ray technique
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