Cross-coupling of arene–gold(III) complexes |
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Authors: | Manuel Hofer Cristina Nevado |
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Institution: | Organic Chemistry Institute, University of Zürich, Winterthurerstrasse 190, CH-8057 Zürich, Switzerland |
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Abstract: | The reactivity of electron-deficient arene–gold(III) complexes toward nucleophilic aromatic and heteroaromatic counterparts has been studied. 1-Methylindole proved to be the best reaction partner while trimethoxybenzenes did not react. The ancillary ligand on gold also influenced the reactivity in the order PPh3>PtBu3>IPr. An oxidative cross-coupling starting from the corresponding gold(I) complexes in presence of hypervalent iodide oxidants was also studied. |
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Keywords: | Gold Cross-coupling Oxidation Arenes |
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