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Aromatic Fused [30] Heteroannulenes with NIR Absorption and NIR Emission: Synthesis,Characterization, and Excited‐State Dynamics
Authors:Abhijit Mallick  Juwon Oh  Prof. Dr. Dongho Kim  Prof. Dr. Harapriya Rath
Affiliation:1. Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, Kolkata, India), Fax;2. Department of Chemistry, Yonsei University, Seodaemun-gu, Seoul, Korea;3. +91)?33‐24732805
Abstract:Two hitherto unknown planar aromatic [30] fused heterocyclic macrocycles (1.1.0.1.1.0), with NIR absorption in free‐base form and protonation‐induced enhanced NIR emission, have been synthesized from easy to make precursors. The induced correspondence of fusion on the macrocyclic structure, electronic absorption, and emission spectra have been highlighted.
Keywords:aromaticity  fused heterocycles  heteroannulenes  NIR absorption  NIR emission
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