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Dissymmetry effects on the laser spectroscopy of supersonically expanded rare gas/chiral arene heteroclusters |
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| Authors: | Filippi Antonello Giardini Anna Marcantoni Enrico Paladini Alessandra Piccirillo Susanna Renzi Gabriele Rondino Flaminia Roselli Graziella Satta Mauro Speranza Maurizio |
| Institution: | Dipartimento di Studi di Chimica e Tecnologia delle Sostanze Biologicamente Attive, Università "La Sapienza", Roma, 00185, Italy. |
| Abstract: | The R2PI-TOF spectra of supersonically expanded rare gas/chiral arene heteroclusters have been rationalized in terms of the distortion of the pi-electron density reflecting the different dipole and quadrupole momenta induced in the rare gas atoms by interaction with the opposite pi-faces of the chiral arene itself. |
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