Heat capacities and thermodynamic properties of N-(tert-butoxycarbonyl)-l-phenylalanine (C14H19NO4) |
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Authors: | Z.-M. Zhao L.-X. Sun Z.-C. Tan |
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Affiliation: | (1) Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Dalian, 116023, People’s Republic of China;(2) China Ionic Liquid Laboratory and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, People’s Republic of China; |
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Abstract: | The heat capacities of N-(tert-butoxycarbonyl)-l-phenylalanine (abbreviated to NTBLP in this article), as an important chemical intermediates used to synthesize proteins and polypeptides, were measured by means of a fully automated adiabatic calorimeter over the temperature range from 78 to 350 K. The measured experimental heat capacities were fitted to a polynomial equation as a function of temperature. The thermodynamic functions, H T − H 298.15K and S T − S 298.15K, were calculated based on the heat capacity polynomial equation in the temperature range of (80–350 K) with an interval of 5 K. The thermal stability of the compound was further studied using TG and DSC analyses; a possible mechanism for thermal decomposition of the compound was suggested. |
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