首页 | 本学科首页   官方微博 | 高级检索  
     


Electron transfer processes involving ferrocenes. Electrogeneration and reactivity of an unusual species,the monocyclopentadienyliron radical
Authors:Nabil El Murr  Annie Chaloyard
Affiliation:Laboratoire de Synthèse et d''Electrosynthèse Organometallique, L.A. 33, 6, Bd. Gabriel, 21100 Dijon France
Abstract:The very reactive cyclopentadienyliron species, (RC5H4)Fe, are relatively easily generated by electrochemical reduction of appropriately substituted and readily available ferrocenes. Thus (MeCOC5H4)Fe has been generated by monoelectronic reduction of (MeCOC5H4)2Fe; it reacts with CO leading, after further reduction, to the acetyl cyclopentadienyldicarbonyliron anion. Reactions of this anion give ring-substituted cyclopentadienyldicarbonyliron derivatives containing the electron-withdrawing MeCO substituent.
Keywords:
本文献已被 ScienceDirect 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号