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Chemistry of organosilicon compounds : CXLII. 29Si nmr spectra of some iron and ruthenium complexes containing silicon. Reassignment of the structures of the complexes obtained by the reaction vinyldisilanes and nonacarbonyldiiron
Authors:Hideki Sakurai  Yoshiyasu Kamiyama  Atsushi Mikoda  Toshiaki Kobayashi  Kazuo Sasaki  Yasuhiro Nakadaira
Institution:Department of Chemistry, Faculty of Science, Tohoku University, Aramaki, Aza-Aobo Sendai 980 Japan
Abstract:29Si NMR studies on several iron and ruthenium carbonyl complexes containing silicon revealed that the complexes obtained from vinyldisilanes and nonacarbonyldiiron previously reported to be (η3-1-silapropenyl)tricarbon: iron compounds really are (η2-vinyldisilane)tetracarbonyliron complexes.
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