Isonitrilsynthesen am komplex: V. Desulfurierung von isothiocyanaten in carbonylmetallat-additions-verbindungen |
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| Authors: | Wolf Peter Fehlhammer Andreas Mayr |
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| Institution: | Institut für Anorganische Chemie der Universität Erlangen-Nürnberg, Egerlandstr. 1, D-8520 Erlangen Bundesrepublik Deutschland |
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| Abstract: | The isocyanide complexes Fe(η-C5H5)(CO)2CNR]PF6] and Cr(CO)5CNR (R = CH3, C6H11, C6H5) are conveniently prepared at ?50°C from carbonyl metallates, isothiocyanates, and phosgene. At room temperature NaFe(η-C5H5)(CO)2] reacts with isothiocyanates () to give the isocyanide bridged complexes Fe2(η-C5H5)2(μ-CO)(μ-CNR)(CO)2]. |
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