Metallorganische verbindungen des 1,2-diethinylbenzols vom typ o-C6H4(CCMR3)2 (M = Si,Ge, Pb) |
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| Authors: | R. Nast H. Grouthi |
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| Affiliation: | Institut für Anorganische und Angewandte Chemie der Universität Hamburg, Martin-Luther-King-Platz 6, 2 Hamburg 13 Deutschland |
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| Abstract: | The preparation of the compounds o-C6H4(CCMR3)2 (M = Si, Ge, Pb; R = CH3; M = Pb; R = C6H5) is described. Their properties are compared with those of o-C6H4(CCSnR3)2 (R = CH3, C6H5) and those of their p-isomers. The structures and bonding conditions proposed for these molecules are supported by dipole measurements, mass spectroscopy, IR, Raman, 1H NMR and 13C NMR data. |
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| Keywords: | Korrepondenz-Autor. |
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