Novel species in the electrochemical reduction of a metalmetal bond bridged by a bidentate fluorophosphine |
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| Authors: | A Chaloyard N El Murr RB King |
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| Institution: | Laboratoire de Synthèse et d''Electrosynthèse Organométallique, Faculté des Sciences, Université de Dijon, 6 Bd Gabriel, 21100 Dijon France;Department of Chemistry, University of Georgia, Athens, Georgia 30602 U.S.A. |
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| Abstract: | The purple bridged bimetallic complex CH3N(PF2)2]3Co2(CO)2 undergoes successive chemically and electrochemically reversible one-electron reductions to the corresponding green radical anion and pale-yellow dianion. The radical anion is relatively unreactive towards oxygen and methyl iodide. The dianion is not only reactive towards oxygen and methyl iodide but also captures small positively charged species (e.g. Li+ and H+) with significant alteration of its chemical properties. |
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| Keywords: | Author to whom correspondence should be addressed |
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