Electrochromatography with a 2.7 mm inner diameter monolithic column |
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Authors: | Qu Qi-shu He You-zhao Gan Wu-er Deng Ning Lin Xiang-qin |
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Institution: | Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, PR China. |
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Abstract: | Monolithic columns of 2.7 mm I.D. have been prepared and used in electrochromatography (EC) separation. Although capillary electrochromatography (CEC) has higher separation efficiency, it displays some shortcomings, such as limited sample loadability and restricted concentration detectability etc. In this paper, we investigate the feasibility of EC separation with millimeter diameter monolithic columns. By using a designed preparation method of monolithic column packed with about 150 microm quartz sand, the effect of Joule heating can be reduced, and the processes of frit making and column packing can be avoided. The concentration detectability of the EC is improved comparing with that of CEC. Moreover, the separation efficiency of 52,000 plates/m was achieved with a 70 mm length and 2.7 mm I.D. monolithic column. |
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