Reactions of metallated 1-hydroxy-2,2,4,5,5-pentamethyl-3-imidazoline with electrophiles |
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| Authors: | V. A. Reznikov L. A. Vishnivetskaya L. B. Volodarskii |
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| Affiliation: | (1) Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrent'eva, 630090 Novosibirsk, Russian Federation |
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| Abstract: | Reactions of metallated 1-hydroxy-2,2,4,5,5-pentamethyl-3-imidazoline with electrophilic reagents followed by oxidation result in mono- and bifunctional substituted nitroxides of 3-imidazoline and an imidazolidine series including enaminocarbonyl and -thiocarbonyi derivatives and enaminoimines, the spin-labeled chelating reagents.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1612–1616, September, 1993. |
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| Keywords: | nitroxyl radical 3-imidazoline enaminoketone enaminoimme enaminoamide enaminothioamide imine metallation |
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