Synthesis of 4-bromocubane-1-carbaldehyde |
| |
| Authors: | A V Shastin V V Zakharov G P Bugaeva L T Eremenko L B Romanova G V Lagodzinskaya G G Aleksandrov I L Eremenko |
| |
| Institution: | (1) Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation;(2) N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991 Moscow, Russian Federation |
| |
| Abstract: | Oxidation of 4-bromo-1-hydroxymethylcubane and 1,4-bis(hydroxymethyl)cubane with the 2,2,6,6-tetramethylpiperidine-N-oxyl-trichloroisocyanuric acid-sodium bicarbonate system afforded the corresponding aldehydes. 4-Bromocubanecarbaldehyde
was also obtained in high yield by reduction of 4-bromocubanecarboxylic acid and its methyl ester with bis(N-methylpiperazinyl)aluminum hydride.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1256–1258, July, 2006. |
| |
| Keywords: | cubane derivatives aldehydes oxidation reduction TEMPO aluminum hydrides X-ray diffraction analysis |
| 本文献已被 SpringerLink 等数据库收录！ |
|
