Intramolekulare Basenkoordination je nach Bedarf: Der 1-(Dimethylaminoethyl)-2,3,4,5-tetramethylcyclopentadienyl-Ligand in der Komplexchemie von s-, p-, d- und f-Block-Elementen |
| |
| Authors: | Peter Jutzi Jü rgen Dahlhaus and Marc O Kristen |
| |
| Institution: | Fakultät für Chemie der Universität Bielefeld Universitätsstraße, W-4800 Bielefeld 1 Deutschland |
| |
| Abstract: | The synthesis of cyclopentadienyl complexes containing the polydentate C5Me4(CH2CH2NMe2) ligand is described. The compounds (C5Me4CH2CH2NMe2)2M (M = Ca, Sm), (C5Me4CH2CH2 NMe2)AIEt2, (C5Me4CH2CH2NMe2)M(CO)2]2 (M = Mo, Fe) and (C5Me4CH2CH2NMe2)Fe(CO)2]+BF4± are obtained by standard procedures. Except for the dimeric metal carbonyls, all cyclopentadienyl compounds are characterized by an additional intramolecular coordination of the nitrogen atom in the side chain. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
