| 1-[1-(4-氯苯基)环丁基]-3-甲基丁胺席夫碱的合成、表征及晶体结构 |
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| 引用本文： | 彭振山,陈福平,刘建湘,蔡铁军. 1-[1-(4-氯苯基)环丁基]-3-甲基丁胺席夫碱的合成、表征及晶体结构[J]. 化学通报, 2009, 72(9) |
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| 作者姓名： | 彭振山 陈福平 刘建湘 蔡铁军 |
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| 作者单位： | 湖南科技大学化学化工学院,理论化学与分子模拟省部共建教育部重点实验室,湘潭,411201;中国地质大学材料科学与化学工程学院,武汉,430074 |
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| 基金项目： | 湖南省教育厅重点科学研究项目 |
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| 摘 要： | 采用减肥药盐酸西布曲明的中间体1-[1-(4-氯苯基)环丁基]-3-甲基丁胺分别与水杨醛、3,5-二氯水杨醛缩合,得到相应的席夫碱化合物2-[[1-[1-(4-氯苯基)环丁基]-3-甲基丁亚氨基]甲基]苯酚(1)和2,4-二氯-6-[[1-[1-(4-氯苯基)环丁基]-3-甲基丁亚氨基]甲基]苯酚(2).通过单晶X-射线衍射、红外光谱、核磁共振谱、元素分析等表征确定了两个席夫碱化合物的组成及结构.1是单斜晶体,空间群C2/c.2是三斜晶体,空间群P-1.化合物主要通过氢键或π-π相互作用形成超分子结构.两个席夫碱化合物具有相似的荧光性质,是潜在多功能蓝色荧光材料.
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| 关 键 词： | 席夫碱 晶体结构 荧光性能 超分子 |
Syntheses,Characterizations and Crystal Structures of the Schiff Bases Derived from 1-[1-(4-chlorophenyl)cyclobutyl]-3-methylbutylamine |
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| Pen Zhenshan,Chen Fuping,Liu Jianxiang,Cai Tiejun. Syntheses,Characterizations and Crystal Structures of the Schiff Bases Derived from 1-[1-(4-chlorophenyl)cyclobutyl]-3-methylbutylamine[J]. Chemistry, 2009, 72(9) |
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| Authors: | Pen Zhenshan Chen Fuping Liu Jianxiang Cai Tiejun |
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| Affiliation: | ~1 School of Chemistry & Chemical Engineering;Key Laboratory of Theoretical Chemistry and Molecular Simulation of Ministry of Education;Hunan University of Science & Technology;Xiangtan 411201;~2 The Faculty of Materials Science and Chemical Engineering;China University of Geoscience;Wuhan 430074 |
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| Abstract: | The Schiff bases of 2-[[1-[1-(4-chlorophenyl)cyclobutyl]-3-methylbutylimino]methyl]phenol(1) and 2,4-dichloro-6-[[1-[1-(4-chlorophenyl)cyclobutyl]-3-methylbutylimino]methyl]phenol (2) had been synthesized by condensation reactions of the 1-[1-(4-chlorophenyl)cyclobutyl]-3-methylbutylamine of the intermediate of Sibutramine hydrochlorid with aldehydes. They had been characterized by the single crystal x-ray diffraction,IR,~1H NMR,~ 13 C NMR and elemental analysis. The compound 1 belongs to monoclinic system ... |
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| Keywords: | Schiff base Crystal structures Fluorescent properties Supramolecular |
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